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dc.contributor.authorVaitla, Janakiram
dc.contributor.authorHopmann, Kathrin H.
dc.contributor.authorBayer, Annette
dc.date.accessioned2018-07-04T12:27:41Z
dc.date.available2018-07-04T12:27:41Z
dc.date.issued2017-11-22
dc.description.abstractA convenient strategy for the synthesis of sulfur ylides via rhodium-catalyzed coupling of in situ generated iodonium ylides with sulfides or sulfoxides has been developed. A wide range of sulfur ylides were obtained in moderate to good yields from inexpensive sulfur compounds and active methylene compounds with a short reaction time (MW, 5–10 min) or 12–16 h at rt. Furthermore, these sulfoxonium ylides were used as novel acceptor/acceptor carbenes for N–H insertion reactions.en_US
dc.description.sponsorshipThe Tromsø Research Foundation (TFS2016KHH)en_US
dc.descriptionAccepted manuscript version. Published version available at <a href=https://doi.org/10.1021/acs.orglett.7b03413> https://doi.org/10.1021/acs.orglett.7b03413</a>.en_US
dc.identifier.citationVaitla, J., Hopmann, K.H. & Bayer, A. (2017). Rhodium-Catalyzed Synthesis of Sulfur Ylides via in Situ Generated Iodonium Ylides. Organic Letters, 19(24), 6688-6691. https://doi.org/10.1021/acs.orglett.7b03413en_US
dc.identifier.cristinIDFRIDAID 1518121
dc.identifier.doi10.1021/acs.orglett.7b03413
dc.identifier.issn1523-7060
dc.identifier.issn1523-7052
dc.identifier.urihttps://hdl.handle.net/10037/13156
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.journalOrganic Letters
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/FRINATEK/231706/Norway/"Eeny, meeny, miny, moe": Selectivity-determining factors in asymmetric catalysis//en_US
dc.rights.accessRightsopenAccessen_US
dc.subjectVDP::Matematikk og Naturvitenskap: 400::Kjemi: 440en_US
dc.subjectVDP::Mathematics and natural science: 400::Chemistry: 440en_US
dc.titleRhodium-Catalyzed Synthesis of Sulfur Ylides via in Situ Generated Iodonium Ylidesen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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