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dc.contributor.authorThomas, Kolle E
dc.contributor.authorDesbois, Nicolas
dc.contributor.authorConradie, Jeanet
dc.contributor.authorTeat, Simon J.
dc.contributor.authorGros, Claude P
dc.contributor.authorGhosh, Abhik
dc.date.accessioned2020-01-29T06:58:55Z
dc.date.available2020-01-29T06:58:55Z
dc.date.issued2020-01-02
dc.description.abstractGiven that noninnocent and metalloradical-type electronic structures are ubiquitous among dipyrrin-bisphenolate (DPP) complexes, we synthesized the gold(III) derivatives as potentially innocent paradigms against which the properties of other metallo-DPP derivatives can be evaluated. Electronic absorption spectra, electrochemical studies, a single-crystal X-ray structure, and DFT calculations all suggest that the ground states of the new complexes indeed correspond to an innocent Au<sup>III</sup>–DPP<sup>3−</sup>, paralleling a similar description noted for Au corroles. Interestingly, while DFT calculations indicate purely ligand-centered oxidations, reduction of AuDPP is predicted to occur across both the metal and the ligand.en_US
dc.identifier.citationThomas KE, Desbois, Conradie J, Teat SJ, Gros, Ghosh A. Gold dipyrrin-bisphenolates: A combined experimental and DFT study of metal-ligand interactions. RSC Advances. 2019;10(1):533-540en_US
dc.identifier.cristinIDFRIDAID 1782863
dc.identifier.doi10.1039/c9ra09228e
dc.identifier.issn2046-2069
dc.identifier.urihttps://hdl.handle.net/10037/17247
dc.language.isoengen_US
dc.publisherRoyal Society of Chemistryen_US
dc.relation.journalRSC Advances
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/DEMO2000/263332/Norway/Unmanned Ocean Vehicles for remote marine observations in environmentally sensitive area to oil and gas activities//en_US
dc.rights.accessRightsopenAccessen_US
dc.rights.holderCopyright 2020 The Author(s)en_US
dc.subjectVDP::Mathematics and natural science: 400en_US
dc.subjectVDP::Matematikk og Naturvitenskap: 400en_US
dc.titleGold dipyrrin-bisphenolates: A combined experimental and DFT study of metal-ligand interactionsen_US
dc.type.versionpublishedVersionen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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