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dc.contributor.authorLarsen, Simon
dc.contributor.authorMccormick-Mcpherson, Laura J
dc.contributor.authorTeat, Simon J.
dc.contributor.authorGhosh, Abhik
dc.date.accessioned2020-03-05T09:33:36Z
dc.date.available2020-03-05T09:33:36Z
dc.date.issued2019-04-12
dc.description.abstractAcid-catalyzed condensation of pyrrole, 4-trifluoromethylbenzaldehyde, and azulene, followed by DDQ oxidation, has resulted in the isolation of the novel macrocycle azulicorrole, arguably the first example of a carbacorrole aside from N-confused corrole. Despite poor yields (<1%), the free ligand could be structurally characterized and converted to the formal Cu(III) and Au(III) derivatives, of which the Cu(III) complex could also be structurally characterized. Both the free base and the two metal complexes exhibit richly structured UV–vis spectra that extend well into the near-infrared, suggesting potential applications in bioimaging and photodynamic therapy.en_US
dc.identifier.citationLarsen S, Mccormick-Mcpherson, Teat SJ, Ghosh A. Azulicorrole. ACS Omega. 2019;4(4):6737-6745en_US
dc.identifier.cristinIDFRIDAID 1742743
dc.identifier.doi10.1021/acsomega.9b00275
dc.identifier.issn2470-1343
dc.identifier.urihttps://hdl.handle.net/10037/17635
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.journalACS Omega
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/NANO2021/262229/Norway/Metallocorroles for photodynamic therapy and bioimaging//en_US
dc.rights.accessRightsopenAccessen_US
dc.rights.holderCopyright 2019 The Author(s)en_US
dc.subjectVDP::Mathematics and natural science: 400::Chemistry: 440en_US
dc.subjectVDP::Matematikk og Naturvitenskap: 400::Kjemi: 440en_US
dc.titleAzulicorroleen_US
dc.type.versionpublishedVersionen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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